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The inclusion of pyronine B and pyronine Y by beta- and gamma-cyclodextrins A kinetic and equilibrium study
Authors:Robert L Schiller  Stephen F Lincoln  John H Coates
Institution:(1) Department of Physical and Inorganic Chemistry, University of Adelaide, 5001 Adelaide, South Australia
Abstract:Equilibrium and temperature-jump spectrophotometric studies show that the mono-cation of pyronine B (PB) is included by beta- and gamma-cyclodextrins (betaCD and gammaCD) to form the labile complexes PB. betaCD, PB. gammaCD and (PB)2. gammaCD in water. The equilibrium, kinetic and structural aspects of these complexes and those formed by pyronine Y are discussed in conjunction with data characterizing the inclusion of other dyes by cyclodextrins.
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