The inclusion of pyronine B and pyronine Y by beta- and gamma-cyclodextrins A kinetic and equilibrium study |
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Authors: | Robert L Schiller Stephen F Lincoln John H Coates |
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Institution: | (1) Department of Physical and Inorganic Chemistry, University of Adelaide, 5001 Adelaide, South Australia |
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Abstract: | Equilibrium and temperature-jump spectrophotometric studies show that the mono-cation of pyronine B (PB) is included by beta- and gamma-cyclodextrins ( CD and CD) to form the labile complexes PB. CD, PB. CD and (PB)2. CD in water. The equilibrium, kinetic and structural aspects of these complexes and those formed by pyronine Y are discussed in conjunction with data characterizing the inclusion of other dyes by cyclodextrins. |
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