Solvophobic effects in binary nonaqueous mixtures |
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| Authors: | M. V. Kulikov A. M. Zaichikov |
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| Affiliation: | (1) Institute of Chemistry of Non-Aqueous Solution, Russion Academy of Sciences, 1 ul. Akademicheskaya, 153045 Ivanova, Russian Federation;(2) Ivanova State Academy of Chemistry and Technology, 7 prosp. F. Engel'sa, 153460 Ivanovo, Russian Federation |
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| Abstract: | In the framework of the Mc Millan-Mayer theory, the enthalpy, volume, and heat capacity coefficients of binary and ternary interactions of amides, alcohols, and acetonitrile in water and nonaqueous solvents were obtained at various temperatures. No pronounced regularities in changes in the coefficients of multiple interactions observed in aquous solutions were found for nonaqueous solutions of the substances studied. None of the considered coefficients can be used as a criterion for solvophobicity. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1587–1591, September, 1997. |
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| Keywords: | aqueous and nonaqueous solutions amides alcohols acetonitrile McMillan— Mayer theory coefficients of binary and ternary interactions solvophobic effects hydrophobic hydroation criteria for hydrophobicity |
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