Gas-phase methylation of [60]fullerene |
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| Authors: | Vieira S M C Drewello T Kotsiris S G Rego C A Birkett P R |
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| Institution: | Division of Chemistry and Materials, School of Biology, Chemistry & Health Science, Manchester Metropolitan University, Chester Street, Manchester, M1 5GD, United Kingdom. smc81@eng.cam.ac.uk |
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| Abstract: | Direct methylation of 60]fullerene via a gas-phase reaction in a CH4/H2 atmosphere was performed using a modified hot filament chemical vapor deposition method. Pressures were varied from 10 to 60 mbar and the substrate was maintained at 690 degrees C. High-resolution matrix-assisted laser desorption ionization (MALDI) mass spectrometry analysis showed signals corresponding to C60H18-2n(H,CH3)n. Collision-induced dissociation experiments confirmed a maximum of 18 ligands possible to the 60]fullerene cage. |
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