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Thermal fracture of plastics
Authors:A Cross  R N Haward
Abstract:The extension and fracture under tension of poly(vinyl chloride) strips of different lengths have been studied. It was found that, in spite of decreasing strain rate, long pieces are subject to a type of brittle fracture (necking rupture) occurring immediately after neck formation. This result, which could be expected from previous work, is shown to depend on the elastic energy stored in the longer test pieces. This energy is converted to heat under conditions of neck formation, leading to a temperature rise of 24 ± 4°C, determined by a thermal imaging system. With short test pieces the rise in temperature is much smaller, and a transition to stable neck propagation occurs. Optical and electron micrographs provide additional evidence of heating at the fracture surface. A semiquantitative treatment of the adiabatic process gives upper and lower limits for the predicted temperature change neglecting thermal losses. It is also possible to estimate a minimum length for the initiation of adiabatic deformation. Both calculations give results in reasonable agreement with experiments. Observations with polycarbonate show a similar length effect at low temperatures.
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