Metallbindungsphänomene: Alkoholat-Aggregate als unmittelbare Teilnehmer an Eliminierungsreaktionen |
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| Authors: | Manfred Schlosser Grald Jan Edeline Byrne Ji&#x;i Sicher |
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| Institution: | Manfred Schlosser,Gérald Jan,Edeline Byrne,Jiři Sicher |
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| Abstract: | In solvents of low polarity it is neither a monomolecular nor a dissociated alcoholal species which effects dehydrohalogenation of vic-dihaloalkanes and vic-dihalocycloalkanes but rather a dimeric, trimeric or tetrameric alcoholate aggregate. This behavior has important implications for the stereochemical outcome of such elimination reactions. |
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