Massenspektrometrische Untersuchung aromatischer Halogenide der Summenformel C9H11Cl: Mechanismus der Äthylen-Abspaltung aus dem Ion [M ? Cl]+˙ |
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Authors: | Claus K ppel,Helmut Schwarz,Ferdinand Bohlmann |
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Affiliation: | Claus Köppel,Helmut Schwarz,Ferdinand Bohlmann |
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Abstract: | By investigation of isomeric 2H- and 13C-labelled C9H11 Cl-compounds it has been shown that the ion [M ? Cl]+ is transformed mainly to the ion [C7H7]+ via C2H4-elimination from alkyl-substituted tropylium-ions. Phenyl-cyclopropane-cations play only a small part, if at all, in this fragmentation process. |
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