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Quantitative theory of chemically induced dynamic nuclear polarisation in high magnetic fields
Authors:A. L. Buchachenko  Sh. A. Markarian
Abstract:Further development of the diffusional model of the radical pair is suggested. A function is proposed for the exponential distribution of the diffusional trajectories of the radicals in a radical pair. By this function, the differences in the populations of nuclear spin levels in the molecules are calculated for the S, T and U precursor pairs. The equations which express the relationship between the theoretically calculated population differences and the experimentally determined enhancement coefficients are derived.
Keywords:
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