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聚合物纳米粒子乳液的制备及性能研究——添加组分对乳胶粒子形态及胶膜吸水率的影响
引用本文:侯有军,任力,罗正汤,曾繁森.聚合物纳米粒子乳液的制备及性能研究——添加组分对乳胶粒子形态及胶膜吸水率的影响[J].离子交换与吸附,2001,17(1):70-77.
作者姓名:侯有军  任力  罗正汤  曾繁森
作者单位:华南理工大学材料学院,广州,510641
基金项目:广东省自然科学基金(顺序号:990617)
摘    要:本文采用种子微乳液聚合方法,经后期氨化反应,合成了聚丙烯酸酯纳米粒子乳液,讨论了乳化剂、缓冲剂和水溶性丙烯酸单体等添加组分对乳粒子形态和胶膜吸水率的影响,并探讨了微乳液聚合的反应机理。

关 键 词:种子微乳液聚合  氨化反应  聚合物纳米粒子乳液  乳胶粒子形态  胶膜吸水率  聚丙烯酸酯
文章编号:1001-5493(2001)01-0070-08
修稿时间:2000年3月9日

THE STUDY OF SYNTHESIS AND BEHAVIOR OF POLYMER NANOMETER EMULSIONS -The Influence of Additives on Morphology of Emulsion Particle and Rate of Water-Absorbability of Film
HOU Youjun,REN Li,LUO Zhengtang,ZENG Fansen.THE STUDY OF SYNTHESIS AND BEHAVIOR OF POLYMER NANOMETER EMULSIONS -The Influence of Additives on Morphology of Emulsion Particle and Rate of Water-Absorbability of Film[J].Ion Exchange and Adsorption,2001,17(1):70-77.
Authors:HOU Youjun  REN Li  LUO Zhengtang  ZENG Fansen
Institution:HOU Youjun REN Li LUO Zhengtang ZENG Fansen Institute of Polym. Mat. Sci. and Eng.,South China University of Technology,Guangzhou,510640
Abstract:In this paper, the polyacrylate nanoparticle emulsions was synthesized by the methods of seed microemulsion polymerization and final ammonification. We discussed the influence of the additives such as emulsifier, buffering agent and acrylic acid on the morphology of nanoparticles and the rate of water-absorbability of film, and then investigated the mechanism of emulsion polymerization. Key word: Nanoparticle, Emulsion polymerization, Seed microemulsion polyerization, Ammonification.
Keywords:Nanoparticle  Emulsion polymerization  Seed microemulsion polyerization  Ammonification  
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