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Simultaneous Determination of Ascorbic Acid and Uric Acid by Using a PVC/TTF‐TCNQ Composite Electrode as Detector in a FIA System
Authors:Manuel Cano  Beatriz Palenzuela  J?Luis Ávila  Rafael Rodríguez‐Amaro
Institution:Departamento de Química Física y Termodinámica Aplicada, Universidad de Córdoba, Campus de Rabanales, Edificio C‐3, 14071?Córdoba, Spain
Abstract:A PVC/TTF‐TCNQ composite electrode has been employed as detector in a flow injection system. The proposed method allows the simultaneous detection of ascorbic acid (AA) and uric acid (UA) in mixtures by using a FIA system in a simple manner, without pre‐treatment or modified electrode. This method is based on the amperometric determination of (a) ascorbic acid at 0.15 V and (b) both analytes at 0.35 V, being the response linear in the range 1×10?2–4×10?4 M for both analytes with detection limits (S/N=3) of 1.2×10?4 M and 8.1×10?5 M for AA and UA, respectively.
Keywords:TTF‐TCNQ  Composite electrode  PVC  Ascorbic acid  Uric acid  Flow injection
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