Efficient Synthesis of Trialkyl 3‐Phenylbuta‐1,3‐diene‐1,2,4‐tricarboxylates by a Novel One‐Pot Multicomponent Reaction |
| |
| Authors: | Issa Yavari Loghman Moradi Ako Mokhtarporyani‐Sanandej Anvar Mirzaei |
| |
| Institution: | 1. Chemistry Department, Tarbiat Modarres University, P.O. Box 14115‐175, Tehran, Iran, (phone: +?98‐21‐88006631;2. fax: +?98‐21‐88006544) |
| |
| Abstract: | Alkyl 2‐nitroacetates 2 react with alkyl phenylpropiolates 1 in the presence of Ph3P in a mechanistically novel reaction to afford trialkyl 3‐phenylbuta‐1,3‐diene‐1,2,4‐tricarboxylates in yields of 60–80% under neutral conditions. |
| |
| Keywords: | Buta‐1 3‐dienes Phosphine triphenyl‐ Acetates alkyl 2‐nitro‐ Propiolates alkyl phenyl‐ Multicomponent reaction One‐pot multicomponent reaction |
|
|
