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Amperometric Glucose Biosensor Based on Platinum Nanoparticles Combined Aligned Carbon Nanotubes Electrode
Authors:Kun Zhao  Shuqi Zhuang  Zhu Chang  Haiyan Songm  Liming Dai  Pingang He  Yuzhi Fang
Affiliation:1. Department of Chemistry, East China Normal University, 200062, Shanghai, P.?R. China;2. Department of Chemical and Materials Engineering, College of Engineering,University of Dayton, 300 College Park, Dayton, Ohio 45469, USA
Abstract:A sensitive amperometric glucose biosensor based on platinum nanoparticles (PtNPs) combined aligned carbon nanotubes (ACNTs) electrode was investigated. PtNPs which can enhance the electrocatalytic activity of the electrode for electrooxidating hydrogen peroxide by enzymatic reaction were electrocrystallized on 4‐aminobenzene monolayer‐grafted ACNTs electrode by potential‐step method. These PtNPs combined ACNTs' (PtNPs/ACNTs) surfaces were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The highly dispersed PtNPs on ACNTs can be obtained. The enzyme electrode exhibits excellent response performance to glucose with linear range from 1×10?5–7×10?3 mol L?1 and fast response time within 5 s. Furthermore, this glucose biosensor also has good reproducibility. It is demonstrated that the PtNPs/ACNTs electrode with high electrocatalytic activity is a suitable basic electrode for preparing enzyme electrodes.
Keywords:Glucose  Biosensor  Aligned carbon nanotubes electrode  Pt nanoparticles  Electrocatalytic
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