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Phenylpropanoid‐Substituted Catechins and Epicatechins from Smilax china
Authors:Hui‐Lian Huang  Zhi‐Qiang Lu  Guang‐Tong Chen  Jin‐Qiang Zhang  Wei Wang  Min Yang  De‐An Guo
Institution:1. Shanghai Research Center for Modernization of Traditional Chinese Medicine, Shanghai Institute of Materia Medica, Shanghai Institute for Biological Sciences, Chinese Academy of Sciences, 199 Guo Shoujing Road, Zhangjiang, Shanghai 201203, P.?R. China, (phone: +86‐21‐50271516;2. fax: +86‐21‐50272789);3. College of Traditional Chinese Material Medica, Chinese Pharmaceutical University, Nanjing 210009, P.?R. China
Abstract:The four new phenylpropanoid‐substituted catechins 1, 3 , and 4 and 3‐epicatechin ( 2 ), together with seven analogues, were isolated from the AcOEt extract of Smilax china L. (catechin=(2R,3S)‐2‐(3,4‐dihydroxyphenyl)‐3,4‐dihydro‐2H‐2‐benzopyran‐3,5,7‐triol). Their structures were determined by means of spectroscopic analyses, including HR‐MS, IR, 1H‐ and 13C‐NMR, and 2D experiments (COSY, HSQC, and HMBC), and comparison with known related compounds.
Keywords:Smilax china  Phenylpropanoids  Propanoids  phenyl‐  Catechins  Epicatechins
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