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Effect of Casting Solvent on Morphology and Physical Properties of Partially Sulfonated Polystyrene‐block‐poly(ethylene‐ran‐butylene)‐block‐polystyrene Copolymers
Authors:Jinhwan Kim  Bokyung Kim  Bumsuk Jung  Yong Soo Kang  Heung Yong Ha  In‐Hwan Oh  Kyo Jin Ihn
Abstract:The effect of casting solvent on the morphology of sulfonated polystyrene‐block‐poly(ethylene‐ran‐butylene)‐block‐polystyrene (SSEBS) was investigated using transmission electron microscopy and small‐angle X‐ray scattering. Proton conductivities and methanol permeabilities were measured and the related impact on morphological changes is discussed. SSEBS is transformed from a well‐ordered lamellar to a disordered structure as the concentration of MeOH in MeOH/THF mixtures increases.
Keywords:block copolymers  fuel cell membranes  methanol permeability  morphology  proton conductivity
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