Electronic Spectroscopy of UO |
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| Affiliation: | 1. Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604, USA;2. Department of Chemistry, Emory University, Atlanta, GA 30322, USA;1. Department of Materials Science and Engineering, The Nelson Mandela African Institution of Science and Technology (NM-AIST), Arusha, Tanzania;2. Department of Chemistry, University of Dar es Salaam, Tanzania;1. Doctoral School of Sciences and Technology, (EDST), PRASE, Lebanese University, Lebanon;2. Center for Educational Research and Pedagogical Development, CRPD, Dekwaneh, Lebanon;3. Faculty of Engineering-Branch (III), Lebanese University, Hadat Campus, Lebanon;4. Departament de Química Física i Analítica, Universitat Jaume I, Av. de Vicent Sos Baynat, 12007 Castelló de la Plana, Spain;1. University of Missouri – St. Louis, Department of Chemistry and Biochemistry & Center for Nanoscience, United States;2. Southern Illinois University Edwardsville, Department of Chemistry, United States |
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| Abstract: | Spectra for gas-phase uranium oxide have been analyzed to obtain molecular constants and provide a partial atlas of the visible and near infrared bands for the isotopomers238U16O,238U18O,235U16O, and235U18O. Nineteen bands of the238U16O,238U18O, and235U18O isotopomers were rotationally analyzed. With few exceptions, Ω assignments were unambiguously determined from observations of the first lines in at least two rotational branches. Accurate term values and rotational constants are reported. |
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