| 高氯酸银催化炔丙醇与酸酐反应制备烯二酮 |
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| 引用本文： | 原晔,段康,柴多镇,卜超,李卫伟,Francis Verpoort.高氯酸银催化炔丙醇与酸酐反应制备烯二酮[J].分子催化,2024,38(2):104-111. |
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| 作者姓名： | 原晔 段康 柴多镇 卜超 李卫伟 Francis Verpoort |
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| 作者单位： | 武汉理工大学,武汉理工大学,武汉理工大学,武汉理工大学,武汉理工大学,武汉理工大学 |
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| 基金项目： | 国家自然科学基金（No. 22102127） |
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| 摘 要： | 烯二酮类化合物是一类重要的工业原料和多功能的有机合成中间体，在制药工程、香料加工和化学合成中有着广泛的应用。利用高氯酸银（AgClO4）催化炔丙醇与酸酐的反应，首次合成了几种此前从未报道过的新型烯二酮类化合物。该反应过程无需溶剂，且具有操作简单、条件温和、绿色环保、底物普适性广等优点，这表明了该方法在烯二酮合成领域巨大的应用潜力。
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| 关 键 词： | 烯二酮 炔丙醇 高氯酸银 酸酐 催化 |
| 收稿时间： | 2024/1/17 0:00:00 |
| 修稿时间： | 2024/2/6 0:00:00 |
Synthesis of Alkenyl Diketones from Propargylic Alcohols and Anhydrides Catalyzed by Silver Perchlorate |
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| YUAN Ye,DUAN Kang,CHAI Duo-zhen,BU Chao,LI Wei-wei and Francis Verpoort.Synthesis of Alkenyl Diketones from Propargylic Alcohols and Anhydrides Catalyzed by Silver Perchlorate[J].Journal of Molecular Catalysis (China),2024,38(2):104-111. |
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| Authors: | YUAN Ye DUAN Kang CHAI Duo-zhen BU Chao LI Wei-wei and Francis Verpoort |
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| Institution: | Wuhan University of Technology,Wuhan University of Technology,Wuhan University of Technology,Wuhan University of Technology,Wuhan University of Technology,Wuhan University of Technology |
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| Abstract: | Alkenyl diketones are important industrial materials and multifunctional organic intermediates, which have extensive applications in pharmaceutical engineering, fragrance processing and chemical synthesis. In this study, several unprecedented alkenyl diketones has been successfully synthesized for the first time, through the reaction of propargylic alcohols and anhydrides with silver perchlorate (AgClO4) as the catalyst. This solvent-free reaction process has the advantages of simple operation, mild conditions, eco-friendliness, and wide substrate scope, implying its great potential for the synthesis of alkenyl diketones. |
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| Keywords: | alkenyl diketone propargylic alcohol silver perchlorate anhydride catalysis |
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