Permanent electric dipole moment of molybdenum carbide |
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Authors: | Wang Hailing Virgo Wilton L Chen Jinhai Steimle Timothy C |
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Institution: | Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287-1604, USA. |
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Abstract: | High resolution optical spectroscopy has been used to study a molecular beam of molybdenum monocarbide (MoC). The Stark effect of the R(e)(0) and Q(fe)(1) branch features of the 18.6] (3)Pi(1)-X (3)Sigma(-)(0,0) band system of (98)MoC were analyzed to determine the permanent electric dipole moments mu(e) of 2.68(2) and 6.07(18) D for the 18.6] (3)Pi(1)(nu=0) and X (3)Sigma(-)(nu=0) states, respectively. The dipole moments are compared with the experimental value for ruthenium monocarbide T. C. Steimle et al., J. Chem. Phys. 118, 2620 (2003)] and with theoretical predictions. A molecular orbital correlation diagram is used to interpret the observed and predicted trends of ground state mu(e) values for the 4d-metal monocarbides series. |
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