Synthesis, structures and photophysical properties of luminescent copper(I) and platinum(II) complexes with a flexible naphthyridine-phosphine ligand |
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| Authors: | Zhang Jun-Feng Fu Wen-Fu Gan Xin Chen Jian-Hua |
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| Institution: | Laboratory Of Organic Optoelectronic Functional Materials and Molecular Engineering, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, P R China. |
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| Abstract: | Condensation of Ph(2)PH and paraformaldehyde with 2-amino-7-methyl-1,8-naphthyridine gave the new flexible tridentate ligand 2-N-(diphenylphosphino)methyl]amino-7-methyl-1,8-naphthyridine (L). Reaction of L with Cu(CH(3)CN)(4)]BF(4) and/or different ancillary ligands in dichloromethane afforded N,P chelating or bridging luminescent complexes (L)(2)Cu(2)](BF(4))(2), (micro-L)(2)Cu(2)(PPh(3))(2)](BF(4))(2) and (L)Cu(CNN)]BF(4) (CNN = 6-phenyl-2,2'-bipyridine), respectively. Complexes (L)(2)Pt]Cl(2), (L)(2)Pt](ClO(4))(2) and (L)Pt(CNC)]Cl (CNC = 2,6-biphenylpyridine) were obtained from the reactions of Pt(SMe(2))(2)Cl(2) or (CNC)Pt(DMSO)Cl with L. The crystal structures and photophysical properties of the complexes are presented. |
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