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Antimony-121 mössbauer spectra of antimony (III) compounds with a stereochemically active lone pair |
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| Authors: | Masuo Takeda Masashi Takahashi Ryuhichi Ohyama Izumi Nakai |
| Affiliation: | (1) Department of Chemistry, Faculty of Science, Toho University, Fuanabashi-shi, 274 Chiba, Japan;(2) Department of Chemistry, The University of Tsukuba, Sakuramura, 305 Ibaraki, Japan |
| Abstract: | The Sb-121 Mössbauer parameters at 20 K for 23 antimony(III) compounds were obtained and the data are discussed in terms of known crystal structures. The isomer shifts and quadrupole coupling constants depend strongly on the type of configuration around the Sb(III) atoms with stereochemically active lone pair electrons. |
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