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Shift of the optical absorption edge in C60 clathrate single crystals
Authors:K Kamarás  A Breitschwerdt  S Pekker  K Fodor-Csorba  G Faigel  M Tegze
Institution:(1) Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, W-7000 Stuttgart 80, Germany;(2) Research Institute for Solid State Physics, Hungarian Academy of Sciences, P.O. Box 49, H-1525 Budapest, Hungary
Abstract:We measured the transmission between 1.6–2.2 eV of pure C60 and three clathrate single crystals containing different aliphatic guest molecules. The absorption edge in the clathrates shows a blue shift of 0.1 eV irrespective of the guest molecule, indicating that C60 is electronically isolated in these compounds.
Keywords:78  20  Dj
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