Facile N-arylation of amines and sulfonamides and o-arylation of phenols and arenecarboxylic acids |
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Authors: | Liu Zhijian Larock Richard C |
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Institution: | Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA. |
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Abstract: | An efficient, transition-metal-free procedure for the N-arylation of amines, sulfonamides, and carbamates and O-arylation of phenols and carboxylic acids has been achieved by allowing these substrates to react with a variety of o-silylaryl triflates in the presence of CsF. Good to excellent yields of arylated products are obtained under very mild reaction conditions. This chemistry readily tolerates a variety of functional groups. |
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