Physical ageing in Se94Sn6 glass induced by gamma irradiation |
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| Authors: | Mousa MA Imran Ibrahim F Al-Hamarneh MA Al-Ewaisi |
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| Institution: | a Materials Science Laboratory, Department of Applied Science, Prince Abdullah Bin Ghazi Faculty of Science and Information Technology, Al-Balqa’ Applied University, Al-Salt-19117, Jordan
b Department of Computer Science, Faculty of Information Technology, Al-Ahliyya Amman University, Al-Salt, Jordan |
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| Abstract: | A differential scanning calorimeter (DSC) has been used to monitor the influence of high-energy Co60 gamma-irradiation on physical ageing in Se96Sn4 glass. It is observed that the relaxation process in the studied glass is slow after 1 and 3 years of natural storage, and can be highly accelerated by γ-irradiation. The glass transition temperature Tg and the endothermic peak area, which is directly related to the relaxation enthalpy Δh, were found to exhibit a remarkable change after irradiation and also during an additional natural storage for 6 months and 1 year of the irradiated Se96Sn4 glass. Tg value of γ-irradiated glass increases by 12 K; meanwhile, that of additional 6-months- and 1-year-stored glass Tg increases by 19 and 20 K in comparison to its counterpart of 1-year-aged non-irradiated sample. The same trend is also observed for Δh, which becomes 2.33, 3.61 and 3.65 times that of the 1-year-aged non-irradiated case, respectively, for γ-irradiated, additional 6-months- and 1-year-stored glass. These indications reveal that γ-irradiation activates the relaxation of the glass towards a state thermodynamically close to the equilibrium super-cooled liquid state. |
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| Keywords: | Physical ageing Gamma-irradiation Glass transition temperature Relaxation enthalpy |
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