Organosulfur oxidation by hydrogen peroxide using a dinuclear Mn-1,4,7-trimethyl-1,4,7-triazacyclononane complex |
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| Authors: | John R Lindsay Smith Jane Murray Terry R Lowdon |
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| Institution: | a Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom
b C6 Solutions Ltd, Wheldon Road, Castleford, West Yorkshire WF10 2JT, United Kingdom |
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| Abstract: | A mechanistic study of organosulfide oxidation by H2O2, using a dinuclear manganese complex as the catalyst, has revealed an unusual switch in the philicity of the oxidant for the first and the second oxygen transfer steps; this switch has been exploited to tune selectivity for each of the products. |
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| Keywords: | Oxidation Sulfide Sulfoxide Catalysis Manganese 1 4 7-trimethyl-1 4 7-triazacyclononane complexes Hydrogen peroxide |
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