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Excellent diastereoselective allylation of camphor derived glyoxylic oxime ethers mediated by a Lewis acid
Authors:Neelesh A. Kulkarni
Affiliation:Department of Chemistry, National Taiwan Normal University, Taipei 116, Taiwan, ROC
Abstract:The nucleophilic allylation of camphor derived glyoxylic oxime ethers was carried out using allyltributyltin in the presence of Sn(OTf)2 affording the corresponding homoallylic amines in high chemical yields (up to 94%) and excellent stereoselectivities (up to >99%).
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