The first example of anomeric glycoconjugation to phthalocyanines |
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| Authors: | Xavier Alvarez-Mico Thomas Ziegler |
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| Institution: | Institut für Organische Chemie II, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany |
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| Abstract: | Preparation and characterization of peripherally glucose substituted zinc(II) phthalocyanine 6, linked via the anomeric carbon through a novel glycosidation method is reported for the first time, for which classical Pc template chemistry with the unprotected phthalonitrile 4 could be used. Phthalocyanine 6 was formed in high yield and is displaying a high solubility in water as a primary condition for a potential biological application. |
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| Keywords: | Carbohydrates Phthalocyanines Anomeric link |
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