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Chiral 6-phenyl-2,3-bismethylenemethoxycarbonyl-[1,4]-dioxane as a designer synthon for an efficient and short synthesis of optically pure 2,6-dioxabicyclo[3.3.0]octane-3,7-dione
Authors:Ganesh Pandey  Amrut L Gaikwad  Smita R Gadre
Institution:Division of Organic Chemistry (Synthesis), National Chemical Laboratory, Pune 411008, India
Abstract:Chiral 6-phenyl-2,3-bismethylenemethoxycarbonyl-1,4]-dioxane, synthesized by the PET cyclization of 8, has been used as a designer synthon for an efficient and short synthesis of optically pure 2,6-dioxabicyclo3.3.0]octane-3,7-dione.
Keywords:Chiral dioxan  Bis-lactone  Photoinduced electron transfer
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