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Total synthesis of 6-epiprelactone-V via a syn-selective oxygen tethered intramolecular Michael reaction |
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| Authors: | S Chandrasekhar Ch Rambabu S Jaya Prakash |
| Institution: | Organic Chemistry Division, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | The intramolecular protective group (benzylidene acetal) assisted syn-1,3-diol synthesis has been efficiently utilized in a short synthesis of 6-epiprelactone-V starting from (S)-malic acid. |
| Keywords: | Keck allylation Intramolecular oxy-Michael reaction (&minus )-Centrolobine 2 6-Disubstituted tetrahydropyran |
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