The first total synthesis of a tetracyclic antibiotic, (−)-tetrodecamycin |
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| Authors: | Kuniaki Tatsuta Yasuaki Suzuki Akiho Furuyama Hiroshi Ikegami |
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| Affiliation: | Department of Applied Chemistry, School of Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, Japan |
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| Abstract: | (−)-Tetrodecamycin (1) has been synthesized from optically active butenolide through stereoselective SmI2-mediated pinacol cyclization and newly developed deoxygenation. |
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