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An enantiospecific synthesis of (+)-hydroxy-exo-brevicomin
Authors:Kavirayani R. Prasad  Pazhamalai Anbarasan
Affiliation:Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India
Abstract:A concise enantiospecific synthesis of the pine beetle pheromone (+)-hydroxy-exo-brevicomin was achieved from l-(+)-tartaric acid in high yield. The key step involves the reduction of a keto-Weinreb amide derived from tartaric acid.
Keywords:Stereoselective reduction     smallcaps"  >l-(+)-Tartaric acid   Hydroxy-exo-brevicomin
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