A green approach for efficient α-halogenation of β-dicarbonyl compounds and cyclic ketones using N-halosuccinimides in ionic liquids |
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Authors: | H.M. Meshram P.N. Reddy P. Vishnu K. Sadashiv J.S. Yadav |
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Affiliation: | Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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Abstract: | Room temperature ionic liquids (ILs) are used as a green recyclable reaction media for the α-monohalogenation of 1,3-diketones, β-keto-esters and cyclic ketones with N-halosuccinimides in excellent yields in the absence of a catalyst. The recovered ionic liquid was reused five to six times with consistent activity. |
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Keywords: | Ionic liquids Halogenation N-Halosuccinimides β-Dicarbonyl compounds Cyclic ketones |
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