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A green approach for efficient α-halogenation of β-dicarbonyl compounds and cyclic ketones using N-halosuccinimides in ionic liquids
Authors:H.M. Meshram  P.N. Reddy  P. Vishnu  K. Sadashiv  J.S. Yadav
Affiliation:Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:Room temperature ionic liquids (ILs) are used as a green recyclable reaction media for the α-monohalogenation of 1,3-diketones, β-keto-esters and cyclic ketones with N-halosuccinimides in excellent yields in the absence of a catalyst. The recovered ionic liquid was reused five to six times with consistent activity.
Keywords:Ionic liquids   Halogenation   N-Halosuccinimides   β-Dicarbonyl compounds   Cyclic ketones
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