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The first reductive cyclization by lithium aluminum hydride: stereospecific reductive cyclization of 1-(methoxycarbonylmethyl)imidazolidin-4-ones
Authors:Fu-Lin Chen
Affiliation:Department of Chemistry, National Cheng Kung University, Tainan, Taiwan, ROC
Abstract:The first LiAlH4-driven reductive cyclization of the bifunctional 1-(methoxycarbonylmethyl)imidazolidin-4-ones, (−)-1a-c or(+)-1a-c, stereospecifically generated the corresponding 1,6-diaza-4-oxa-bicyclo[3.2.1]octanes, (−)-3a-c or(+)-3a-c, with a novel bicyclic system.
Keywords:Reductive cyclization   Lithium aluminum hydride   Stereospecific reaction
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