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Convenient preparation of tert-butyl esters
Authors:Douglass F Taber  David A Gerstenhaber  Xia Zhao
Institution:Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA
Abstract:A general method is presented for the preparation of tert-butyl esters by the gentle warming of the carboxylic acid in the presence of excess of tert-butyl acetoacetate and a catalytic amount of acid. This method generates only low pressures, and is therefore suitable for laboratory scale pressure glassware.
Keywords:tert-Butyl esters  Isobutylene  tert-Butyl acetoacetate
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