Oxidations with IBX: benzyl halides to carbonyl compounds, and the one-pot conversion of olefins to 1,2-diketones |
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| Authors: | Jarugu Narasimha Moorthy Nidhi Singhal Kalyan Senapati |
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| Institution: | Department of Chemistry, Indian Institute of Technology, Kanpur 208016, India |
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| Abstract: | A variety of benzyl halides were converted to the corresponding aldehydes/ketones in respectable yields by IBX in DMSO at 65 °C. The bromohydrin reaction of olefins using NBS-H2O in DMSO can be nicely adapted to IBX-mediated oxidation of benzyl halides in such a way that olefins are converted to the corresponding 1,2-diketones in good isolated yields in one-pot. |
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