Studies directed towards the total synthesis of clavosolides: synthesis of an isomer of clavosolide A |
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| Authors: | Tushar Kanti Chakraborty Vakiti Ramkrishna Reddy |
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| Affiliation: | Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | The total synthesis of clavosolide A, employing a radical-mediated route to build its substituted tetrahydropyran unit, a Yamaguchi reaction to construct the diolide aglycon and the Schmidt method for the final glycosidation step, revealed that the reported structure is an isomer of the natural product. |
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| Keywords: | Clavosolides Clavosolide A Epoxide opening 2-Methyl-1,3-diol Diolide |
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