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Palladium N-methylimidazolium supported complexes as efficient catalysts for the Heck reaction
Authors:Belen Altava  Amrit Puzary  Victor Sans
Affiliation:Departamento de Química Inorgánica y Orgánica, UAMOA, Universidad Jaume I/CSIC, Campus del Riu Sec, Avenida Sos Baynat, s/n, E-12071 Castellón, Spain
Abstract:Different N-methylimidazolium supported ligands have been easily synthesized. The palladium complexes derived from those materials can be used for the catalysis of the Heck reaction giving excellent yields, selectivities and very good TON and TOF values. The supported Pd-pincer complexes show an increased stability, and provide a clear improvement in the recovery and reuse for the supported catalysts.
Keywords:Supported catalysts   Polymer   Heck reaction   Facilitated chemical synthesis
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