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Molecule-induced homolysis of N-hydroxyphthalimide (NHPI) by peracids and dioxirane. A new, simple, selective aerobic radical epoxidation of alkenes |
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| Authors: | Francesco Minisci Cristian Gambarotti Ombretta Porta Francesco Recupero Veronica Mugnaini |
| Affiliation: | a Politecnico di Milano, Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘G. Natta’, Via Mancinelli 7, I-20131 Milano (MI), Italy b Università di Bologna, Dipartimento di Chimica Organica ‘A. Mangini’, Via S. Giacomo, I-40126 Bologna (BO), Italy |
| Abstract: | Evidences are reported concerning the molecule-induced homolysis of NHPI by peracids and dioxirane; their combination can be utilized for the aerobic free-radical epoxidation of alkenes with selectivity quite different from the well-known epoxidation by peracids. |
| Keywords: | N-Hydroxyphthalimide Epoxides Alkenes Peracids |
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