Ring opening of 2-phenylazetidines with allylsilanes |
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| Authors: | Mathias Domostoj,André Mann |
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| Affiliation: | Laboratoire de Pharmacochimie de la Communication Cellulaire UMR 7175/LC, Faculté de Pharmacie, 74 route du Rhin, BP 60024, 67401 Illkirch, France |
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| Abstract: | N-Activated 2-phenylazetidines were opened regioselectively at the benzylic carbon with various allylsilanes or propargylsilane in the presence of BF3·Et2O, providing amino olefins, precursors of biomolecules such as phenyl-homo-kainoids. |
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