Hydrolysis of Chloro(silyl)olefins in Neutral and Acidic Media |
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| Authors: | Lakhtin V. G. Sheludyakov V. D. Ivanov P. V. Telegina N. P. Chernyshev E. A. |
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| Affiliation: | (1) Gosudarstvennyi nauchno-issledovatel'skii institut khimii i tekhnologii elementoorganicheskikh soedinenii State Research Center of the Russian Federation, Moscow, Russia |
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| Abstract: | Action of water on chloro[chloro(alkoxy)silyl]olefins with various number of chlorines in the unsaturated moiety was studied in acidic and neutral media. Linear and cyclic oligosiloxanes with unsaturated chlorine-containing groups were obtained. Correlation between the hydrolytic stability of the Si-Csp2 bond and the structure of the starting chlorosilylolefin was explored. |
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