Univalent transition metal complexes of arenes stabilized by a bulky terphenyl ligand: differences in the stability of Cr(I), Mn(I) or Fe(I) complexes |
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Authors: | Ni Chengbao Ellis Bobby D Fettinger James C Long Gary J Power Philip P |
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Institution: | Department of Chemistry, University of California, Davis, California 95616, USA. |
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Abstract: | Two univalent transition metal complexes, (micro-eta6:eta6-C7H8){MnAr*-3,5-Pri2}2 () and (eta6-C6H6)FeAr*-3,5-Pri2 () (Ar*-3,5-Pri2=C6H-2,6-(C6H(2)-2,4,6-Pri3)(2)-3,5-Pri2), that have eta6 arene coordination were synthesized by reduction of the corresponding metal halides. The complexes are thermally stable in contrast to the corresponding Cri complexes of benzene or toluene which decompose at room temperature. |
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