Frequency dispersion of the viscoelastic properties of solutions of electrolytes |
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Authors: | S Odinaev D M Akdodov N Sh Sharifov Kh Mirzoaminov |
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Institution: | 1.Tadjik National University,Dushanbe,Tajikistan;2.M.S. Osimi Tadjik Technical University,Dushanbe,Tajikistan |
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Abstract: | Analytical expressions obtained earlier are used to numerically calculate the dynamic coefficients of the bulk ην(ω) and shear η
s
(ω) viscosity and the corresponding modules of their bulk K(ω) and shear μ(ω) elasticity at a certain choice of the model of solution structure in an approximation of the osmotic solution
theory. The potential energy of the interaction between ions Φ
ab
(r) was taken as the sum of the Lennard-Jones potential and the generalized Debye potential, taking into account the configuration
and size of ions. In this approximation, the viscoelastic properties of the NaCl water solution were numerically calculated
over a wide interval of change in the thermodynamic parameters and frequency ranges. Satisfactory agreement with the literature
experimental data was obtained. |
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Keywords: | |
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