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Adsorption of acid yellow dye on flakes of chitosan prepared from fishery wastes
Authors:Javed Iqbal  Feroza Hamid Wattoo  Muhammad Hamid Sarwar Wattoo  Rukhsana Malik  Syed Ahmad Tirmizi  Muhammad Imran  Allah Bux Ghangro
Affiliation:1. Institute of Chemistry, University of the Punjab, Lahore 54590, Pakistan;2. Department of Biochemistry, Pir Mehr Ali Shah Arid Agriculture University, Rawalpindi 46300, Pakistan;3. Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan;4. Institute of Biochemistry, University of Sindh, Jamshoro 76080, Pakistan
Abstract:Chitosan flakes, extracted from prawns and labeo rohita scales, with high adsorption capacity were prepared after chemical treatment and were used to remove acid yellow dye from water. The results showed that adsorption capacity is dependent on pH, initial concentration of dye, BET, Langmuir surface area and pore volume of the adsorbent. In acidic conditions, the polymer amino groups were protonated (positively charged polymer chain), which showed attraction with negative ions of anionic dye. Chitosan from prawns scales showed higher dye adsorption under the same experimental conditions. Adsorption isotherms were developed and equilibrium data fitted well to Langmuir and Freundlich isotherm models.
Keywords:Chitosan  Acid yellow dye  Adsorption
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