Mercury macrocyclic complexes: The synthesis of [Hg([18]aneN2S4)] and [Hg(Me2[18]aneN2S4)]. The single crystal x-ray structure of [Hg([18]aneN2S4)](PF6)2·4/3H2O |
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Authors: | Alexander J Blake Gillian Reid and Martin Schr der |
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Institution: | Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ, Scotland, U.K. |
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Abstract: | Reaction of HgSO4 with one molar equivalent of L{L = 18]aneN2S4 (1,4,10,13-tetrathia-7,16-diazacyclooctadecane) or Me218]aneN2S4 (7,16-dimethyl-1,4,10,13-tetrathia-7,16-diazacyclooctadecane)} in refluxing MeOH-H2O for 15 min affords a colourless solution containing the complex cation Hg(L)]2+. Addition of excess PF6? counterion gives the complex Hg(18]aneN2S4)](PF6)2·4/3H2O as a cream coloured solid. A single crystal X-ray structure determination shows mercury(II) bound to a severely distorted octahedral arrangement of the six macrocyclic donor atoms, Hg---S = 2.655(5), 2.735(4), 2.751(4), 2.639(5) Å, Hg---N = 2.473(11), 2.472(17) Å. The cation is in a rac configuration with the two SCH2CH2NCH2CH2S linkages bound meridionally to the metal centre. |
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