A Mössbauer study of some iron(II) complexes with methyl isocyanide,bipyridine and phenanthroline |
| |
| Authors: | Sandro Calogero Umberto Russo Lucia L. Condorelli Ignazio Fragalà |
| |
| Affiliation: | (1) Laboratorio di Chimica e Tecnologia dei Radioelementi del C.N.R. Corso Stati Uniti, 35100 Padova, Italy;(2) Istituto di Chimica Generale, Università di Padova, 35100 Padova, Italy;(3) Istituto di Chimica Generale, Università di Catania, 95125 Catania, Italy |
| |
| Abstract: | Summary Mössbauer parameters for hexacoordinate iron(II) complexes of the type [Fe(N-N)n(CNMe)m](ClO4)2 (m = 6, 4, 2 or 0; n = 0, 1, 2 or 3; N–N = 2, -bipyridine or 1,10-phenanthroline) have been determined. Treatment by a point-charge model including distortions has been carried out in order to rationalize the quadrupole splittings. A computer program has been developed to handle variable geometry systems. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
