| 铽(Ⅲ)的邻香兰素二胺类双希夫碱配合物的合成和表征 |
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| 引用本文： | 赵国良,李彬,那崇武,刘国发,刘晓勋.铽(Ⅲ)的邻香兰素二胺类双希夫碱配合物的合成和表征[J].无机化学学报,1992,8(2):115-119. |
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| 作者姓名： | 赵国良 李彬 那崇武 刘国发 刘晓勋 |
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| 作者单位： | 浙江师范大学化学系，吉林大学材料科学研究所，吉林大学材料科学研究所，吉林大学材料科学研究所，吉林大学测试中心 金华321004，长春 130023，长春 130023，长春 130023，长春 130023 |
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| 摘 要： | 本文首次合成了邻香兰素(2-羟基-3-甲氧基苯甲醛)与乙二胺、联苯胺、对苯二胺缩合而成的双希夫碱(分别以L~1、L~2、L~3表示)的铽(Ⅲ)配合物。用元素分析、红外光谱、摩尔电导、X-射线粉末衍射物相分析、X-射线光电子能谱、差热及热重分析近代物理化学测试手段,确定了这些配合物的组成和键合情况,并对其结构和某些物理化学性质进行了研究。
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| 关 键 词： | 邻香兰素 双希夫碱 铽配合物 |
| 收稿时间： | 1990/1/15 0:00:00 |
SYNTHESIS AND CHARACTERIZATION OF TERBIUM(III) COMPLEXES OF BIS-SCHIFF BASES FROM O-VANILLIN AND SOME DIAMINES |
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| Zhao Guoliang,Li Bin,Na Chongwu,Liu Guofa and Liu Xiaoxiun.SYNTHESIS AND CHARACTERIZATION OF TERBIUM(III) COMPLEXES OF BIS-SCHIFF BASES FROM O-VANILLIN AND SOME DIAMINES[J].Chinese Journal of Inorganic Chemistry,1992,8(2):115-119. |
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| Authors: | Zhao Guoliang Li Bin Na Chongwu Liu Guofa and Liu Xiaoxiun |
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| Institution: | Department of Chemistry, Zhejiang Normal University, Jinhua 321004,Institute of Material Science, Jilin University, Changchun 130023,Institute of Material Science, Jilin University, Changchun 130023,Institute of Material Science, Jilin University, Changchun 130023 and Center of Measurement, Jilin University, Changchun 130023 |
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| Abstract: | The new solid complexes TbL(NO3)3(L = L1, L2, L3) of terbium(III) nitrate hydrate with bis-Schiff bases derived from o-vanillin and ethylenediamine, bcnzidine, p-phenylenediamine have been synthesized and characterized by elemental analysis, infrared spectra, molar conductance, X-ray powder diffraction analysis, X-ray photoelectron spectra, thermogravimetric(TG) and differential thermal analysis(DTA). The possible structures and some properties were studied. |
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| Keywords: | o-vanillin bis-Schiff base terbium complex |
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