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Trapping Copper Phthalocyanine in a Silica Sono-Xerogel
Authors:R Litrán  E Blanco  M Ramírez-del-solar  L Esquivias
Institution:(1) Departamento de Física de la Materia Condensada, Universidad de Cádiz, Puerto Real, Apdo. 40, 11510 Cádiz, Spain
Abstract:A copper phthalocyanine (CuPc) has been encapsulated in silica. The trapping effects were studied comparing the UV-Vis absorption spectra of some CuPc solutions and composites prepared under different conditions. The trapped organic molecules’ stability was monitored during the gelation and drying processes. Leachability test have been carried out with the aim of checking the trapping efficiency. Hydrolysis water of pH=2 and a molar ratioR w =6 mol acid H2O/mol TMOS leads to a higher CuPc stacking angle homogeneity. The increase of Pc induces a narrower mesopore distribution and helps the stabilization of the composite.
Keywords:copper phthalocyanine  sono-gel  UV-Vis absorption spectra  composite  mesopores
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