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Heterocyclic synthesis using nitrile imines. 4. Synthesis of 3-substituted 1-aryl-1,2,4-triazaspiroalk-2-enes
Authors:Dalloul  H M
Institution:(1) Department of Chemistry, Faculty of Applied Sciences, Al-Aqsa University of Gaza, 4051, Gaza Strip, Isral
Abstract:Cycloalkanone oximes react with C-(2-furoyl)-, C-(2-thenoyl)- and C-(phenylaminocarbonyl)nitrile imines to give unexpected 3-substituted 1-aryl-1,2,4-triazaspiroalk-2-enes rather than the cycloaddition or the cyclocondensation products.For Part 3 see Ref. 1.Published in Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1626–1631, November, 2004.
Keywords:cycloalkanone oxime  nitrile imines  1  2  4-triazaspiro[4  5]dec-2-ene  cycloaddition
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