| Hydrothermal Synthesis and Crystal Structure of a Three-dimensional Compound {Mn（H2O）4（VO）2（PO4）2}n |
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| 引用本文： | WU Yanga JIANG Xiao-Yub ZHANG Quan-Zhengc,CHEN Li-Juanc YU Ya-Qinc CHEN Shu-Meic,HE Xiangc YANG Wen-Binc LU Can-Zhongc②,a.Hydrothermal Synthesis and Crystal Structure of a Three-dimensional Compound {Mn（H2O）4（VO）2（PO4）2}n[J].结构化学,2005,24(3):291-294. |
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| 作者姓名： | WU Yanga JIANG Xiao-Yub ZHANG Quan-Zhengc CHEN Li-Juanc YU Ya-Qinc CHEN Shu-Meic HE Xiangc YANG Wen-Binc LU Can-Zhongc② a |
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| 作者单位： | WU Yanga JIANG Xiao-Yub ZHANG Quan-Zhengc CHEN Li-Juanc YU Ya-Qinc CHEN Shu-Meic HE Xiangc YANG Wen-Binc LU Can-Zhongc② a(College of Chemistry & Materials Science，Fujian Normal University，Fuzhou 350007，China) b(Fujian University of Technology，Fuzhou，Fujian 350007，China) c(State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China) |
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| 基金项目： | The project was supported by the 973 program of the MOST (001CB108906)，the NNSFC (90206040，20073048)，the NSF of
Fujian Province 2002F015，2002J006)，the State Key Lab of Structural Chemistry (030065) and the Chinese Academy of Sciences |
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| 摘 要： | 1 INTRODUCTION Current research interest is focused on the designof structures built up from octahedral and tetrahedralbuilding blocks1]. During the wide investigations intransition-metal phosphates for many years, a num-ber of new mixed transition-metal phosphates havebeen reported2]. A great number of manganese phos-phates were largely discovered as minerals1]. On theother hand, many vanadium phosphates have alsobeen prepared recently partly because of their poten-tial applications …
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| 关 键 词： | 晶体结构 三维空间 化合物 {Mn（H2O）4（VO）2（PO4）2}n 锰 钒 化学结构 合成方法 |
Hydrothermal Synthesis and Crystal Structure of a Three-dimensional Compound {Mn(H2O)4(VO)2(PO4)2}n |
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| WU Yang,JIANG Xiao-yu,ZHANG Quan-Zheng,CHEN Li-juan,YU Ya-qin,CHEN Shu-mei,HE Xiang,YANG Wen-Bin,LU Can-Zhong.Hydrothermal Synthesis and Crystal Structure of a Three-dimensional Compound {Mn(H2O)4(VO)2(PO4)2}n[J].Chinese Journal of Structural Chemistry,2005,24(3):291-294. |
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| Authors: | WU Yang JIANG Xiao-yu ZHANG Quan-Zheng CHEN Li-juan YU Ya-qin CHEN Shu-mei HE Xiang YANG Wen-Bin LU Can-Zhong |
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| Abstract: | The title compound, {Mn(H2O)4(VO)2(PO4)2}n 1, was synthesized by the hydrothermal reaction of Mn(Oac)2, Na2VO3 and H3PO4 in aqueous solution and its crystal structure was determined by X-ray single-crystal analysis. Crystallographic data for 1: H4MnO14P2V2, tetragonal system, space group I4/mmm, a = 6.251(3), c = 13.410(9) (A), Mr = 446.79, V = 524.0(5) (A)3, Z = 2, F(000) = 434, μ = 3.320 mm-1, Dc = 2.832 g/cm3, the final R = 0.0577 for 163 observed reflections (I > 2σ(I)). X-ray crystal structure analysis shows that the vanadium phosphorous oxide layers are further connected by MnII(H2O)4 cations to form a three-dimensional network. |
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| Keywords: | hydrothermal synthesis three-dimensional network |
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