| [（n-C4H9）3SnO2C（CH2）2CO2Sn（C4H9-n）3]：A Novel Three-dimensional Framework Structure of Organotin Complex |
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| 引用本文： | 尹汉东,王传华,马春林,王勇,房海霞. [（n-C4H9）3SnO2C（CH2）2CO2Sn（C4H9-n）3]：A Novel Three-dimensional Framework Structure of Organotin Complex[J]. 结构化学, 2003, 22(4): 387-390 |
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| 作者姓名： | 尹汉东 王传华 马春林 王勇 房海霞 |
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| 作者单位： | Department of Chemistry，Liaocheng Teachers University，Liaocheng 252059，China |
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| 基金项目： | the National Natural Science Foundation of China (No. 20271025)，the Natural Science Foundation of Shandong province (No. Z2001B02)，the State Key Laboratory of Crystal Materials,Shandong University |
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| 摘 要： | The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-crystal diffraction. It belongs to orthorhombic with space group Pccn, a = 20.949(3), b = 17.470(3), c = 20.345(3)A, V= 7446(2)A^3, Z= 8, Dc = 1.242 g/cm^3, μ=1.365 mm^-1, F(000) = 2864, R = 0.0544 and wR = 0.1417. The tin atom is of five-coordination in a trigonal bipyramidal structure by bridging two carboxylate groups in different directions and the resulting structure which contains straight twist large ring channels along the axes of a, b and c is a three-dimensional framework polymer containing two different tin atoms.
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| 关 键 词： | [（n-C4H9）3SnO2C（CH2）2CO2Sn（C4H9-n）3] 三维结构 锡 金属有机配合物 三丁基氯化物 丁二酸 X射线分析 |
[(n-C4H9)3SnO2C(CH2)2CO2Sn(C4H9-n)3]:A Novel Three-dimensional Framework Structure of Organotin Complex |
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| YINHan-Dong WANGChuan-Hua MAChun-Lin WANGYong FANGHai-Xia. [(n-C4H9)3SnO2C(CH2)2CO2Sn(C4H9-n)3]:A Novel Three-dimensional Framework Structure of Organotin Complex[J]. Chinese Journal of Structural Chemistry, 2003, 22(4): 387-390 |
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| Authors: | YINHan-Dong WANGChuan-Hua MAChun-Lin WANGYong FANGHai-Xia |
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| Affiliation: | Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059, China |
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| Abstract: | The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-crystal diffraction. It belongs to orthorhombic with space group Pccn, a = 20.949(3), b = 17.470(3), c = 20.345(3) , V = 7446(2) 3, Z = 8, Dc = 1.242 g/cm3, m = 1.365 mm-1, F(000) = 2864, R = 0.0544 and wR = 0.1417. The tin atom is of five-coordination in a trigonal bipyramidal structure by bridging two carboxylate groups in different directions and the resulting structure which contains straight twist large ring channels along the axes of a, b and c is a three-dimensional framework polymer containing two different tin atoms. |
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| Keywords: | tributyltin glutaric acid crystal structure three-dimensional framework structure |
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