Generation and transport of charge carriers in polyvinylcarbazole

The processes of generation and transport of excess charge carriers in polyvinylcarbazole at room temperature and at 353 K were experimentally studied. The polymer was charged with pulses of electrons at energies of 7 and 50 keV, which differed in both linear energy transfer and track structure. A universal method of investigation based on the combination of the time-of-flight technique in the both (surface and bulk) modes with the measurement of radiation-induced conductivity was used. The radiation-chemical yield of free charges was measured using two independent procedures. It was shown that the radiation chemical yield of free charges at 293 K was somewhat smaller for 7-keV than for 50-keV electrons; in the latter case, G = 1.1 in an electric field of 2 × 10⁷ V/m. The parameters of the generalized physical model were determined for polyvinylcarbazole.