Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5',6'-pyrazine |
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| Authors: | Li Feng Clegg Jack K D'Alessandro Deanna M Goux-Capes Laurence Sciortino Natasha F Keene Tony D Kepert Cameron J |
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| Affiliation: | School of Chemistry, University of Sydney, 2006, Australia. |
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| Abstract: | Three high-spin tetranuclear cobalt(II) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5',6'-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail. |
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