A robust hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex: synthesis and its catalytic application towards Suzuki-Miyaura couplings in aqueous solvents |
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Authors: | Tu Tao Feng Xike Wang Zhixun Liu Xiyu |
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Institution: | Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai, China. taotu@fudan.edu.cn |
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Abstract: | A novel hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex (3) acted as a highly efficient robust recyclable molecular catalyst towards Suzuki-Miyaura coupling reactions in aqueous media and tolerated various functional groups (even heterocycles) with extremely low catalyst loading. |
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